RADICAL-ADDITION TO LEVOGLUCOSENONE, SYNTHESIS OF ANHYDROSUGAR HERBICIDE ANALOGS

Citation
R. Blattner et Dm. Page, RADICAL-ADDITION TO LEVOGLUCOSENONE, SYNTHESIS OF ANHYDROSUGAR HERBICIDE ANALOGS, Journal of carbohydrate chemistry, 13(1), 1994, pp. 27-36
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology
ISSN journal
07328303
Volume
13
Issue
1
Year of publication
1994
Pages
27 - 36
Database
ISI
SICI code
0732-8303(1994)13:1<27:RTLSOA>2.0.ZU;2-A
Abstract
Addition of alkyl radicals to levoglucosenone (5) gave ro-3,4-dideoxy- beta-D-erythro-hexopyranos-2-uloses 7 in moderate to good yields. The 4-C-phenyl ethyl derivative 7a was converted by reduction and methylat ion to the methylene isoster 3 of the powerful herbicide 1.