INTRAMOLECULAR DIELS-ALDER REACTION OF FURANS WITH ALLENYL ETHERS FOLLOWED BY METHYLTHIO GROUP 1,4-REARRANGEMENT

Citation
Hj. Wu et al., INTRAMOLECULAR DIELS-ALDER REACTION OF FURANS WITH ALLENYL ETHERS FOLLOWED BY METHYLTHIO GROUP 1,4-REARRANGEMENT, Tetrahedron letters, 35(5), 1994, pp. 729-732
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
5
Year of publication
1994
Pages
729 - 732
Database
ISI
SICI code
0040-4039(1994)35:5<729:IDROFW>2.0.ZU;2-7
Abstract
The base-catalyzed intramolecular Diels-Alder reactions of the furfury l propargyl ethers la-le gave compounds 6a-6e as the major product res pectively, a novel reaction involving an intramolecular Diels-Alder re action followed by a methylthio group 1,4-rearrangement.