MAGNETIC-FIELD EFFECTS ON HYDROGEN ABSTRACTION OF TRIPLET BENZOPHENONE WITH THIOPHENOL IN AN SDS MICELLAR SOLUTION

Authors
WAKASA M SAKAGUCHI Y HAYASHI H
Citation
M. Wakasa et al., MAGNETIC-FIELD EFFECTS ON HYDROGEN ABSTRACTION OF TRIPLET BENZOPHENONE WITH THIOPHENOL IN AN SDS MICELLAR SOLUTION, Chemistry Letters, (1), 1994, pp. 49-50
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1994
Pages
49 - 50
Database
ISI
SICI code
0366-7022(1994):1<49:MEOHAO>2.0.ZU;2-T
Abstract
The photoreduction of benzophenone with thiophenol was studied by a la ser flash photolysis under the magnetic fields of 0-10 T. The escape y ields of the benzophenone ketyl and phenylthiyl radicals decreased wit h increasing magnetic field strength. The observed magnetic field effe ct can be interpreted by the Ag mechanism in the case of a triplet rad ical pair.