FORMATION AND REACTION OF AZOMETHINE YLIDE BY THE REACTION OF CU(ACAC)2-KETOCARBENOIDS WITH 1,1-DIPHENYLMETHANIMINE

Authors
IBATA T SINGH GS
Citation
T. Ibata et Gs. Singh, FORMATION AND REACTION OF AZOMETHINE YLIDE BY THE REACTION OF CU(ACAC)2-KETOCARBENOIDS WITH 1,1-DIPHENYLMETHANIMINE, Chemistry Letters, (1), 1994, pp. 81-84
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1994
Pages
81 - 84
Database
ISI
SICI code
0366-7022(1994):1<81:FAROAY>2.0.ZU;2-R
Abstract
The reaction of alpha-diazocarbonyl compounds with 1,1-diphenylmethani mine in the presence of Cu(acac)2 afforded the corresponding N-substit uted imines in general together with pyrrolidine and 1,4,6-dioxazocine derivatives (in the reaction of alpha-di azo-4-chloroacetophenone) an d 1,1-diphenyl-2-(4-nitrobenzoyl)ethylene (in the reaction of alpha-di azo-4-nitroacetophenone) through azomethine ylides.