ANOMALOUS ASSOCIATION OF 3,3'-DIETHYLOXADICARBOCYANINE IODIDE IN SATURATED SOLUTIONS OF ACETONE AND WATER

Authors
HIRAGA T TANAKA N KIKUCHI N HAYAMIZU K MORIYA T
Citation
T. Hiraga et al., ANOMALOUS ASSOCIATION OF 3,3'-DIETHYLOXADICARBOCYANINE IODIDE IN SATURATED SOLUTIONS OF ACETONE AND WATER, Chemistry Letters, (1), 1994, pp. 153-156
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1994
Pages
153 - 156
Database
ISI
SICI code
0366-7022(1994):1<153:AAO3II>2.0.ZU;2-B
Abstract
An association of 3,3'-Diethyloxadicarbocyanine Iodide (DODCI) in satu rated solutions has been investigated by means of small angle X-ray sc attering (SAXS), H-1-NMR spectroscopy and photo-emission spectroscoPY. In the investigation by SAXS, we have revealed that DODCI molecules i n a saturated acetone solution exhibit an association with an average diameter of 4.5 nm, which is reasonably supported by H-1-NMR spectrosc opy and we could fairly well understand the structural hierarchy actin g in the formation of the association.