PHOTOLYSIS OF ANS(T-N,S)-[CO(S(O)2CH2COO-S,O-)(TREN)]-N=TERTIARY AMINE NITROGEN, TREN=TRIS(2-AMINOETHYL)AMINE) - LINKAGE AND GEOMETRICAL ISOMERIZATION( (T)

Authors
AKHTER FM KOJIMA M YOSHII T KASHINO S YOSHIKAWA Y
Citation
Fm. Akhter et al., PHOTOLYSIS OF ANS(T-N,S)-[CO(S(O)2CH2COO-S,O-)(TREN)]-N=TERTIARY AMINE NITROGEN, TREN=TRIS(2-AMINOETHYL)AMINE) - LINKAGE AND GEOMETRICAL ISOMERIZATION( (T), Chemistry Letters, (1), 1994, pp. 171-174
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1994
Pages
171 - 174
Database
ISI
SICI code
0366-7022(1994):1<171:POAA>2.0.ZU;2-F
Abstract
On photolysis of trans(t-N,S)-[Co{S(O)2CH2COO-S,O}(tren)]+ with visibl e light, both linkage isomerization (sulfinato-S to sulfinato-O) and g eometrical isomerization (trans to cis) took place to yield cis (t-N,O (S)) - and trans(t-N,O(S))-[Co{OS(O)CH2COO-O,O)(tren)]+ (O(S)=oxygen o f sulfinate group).