Enzyme-resistant starch (RS) from amylomaize VII starch replaced up to
50% of the total shortening (40 parts per 100 parts of flour) and up
to 15% of the flour in a yellow layer cake. Starch gelatinization and
melting of the amylose-lipid complex, as determined by differential sc
anning calorimetry, were delayed by a high concentration (100 parts pe
r 100 parts of flour) of sugar in the cake batter. The melting tempera
ture for RS was also raised by the high concentration of sugar. The en
dothermic peak for melting of RS was decreased by the limiting amount
of water in the cake system. In cakes in which RS replaced 15% of the
flour, no significant effects were recorded on physical characteristic
s (specific gravity of batter, cake weight and volume, water activity,
moisture, and softness [determined by a compression test]) and scanni
ng electron microscopy pictures. Cake batters containing shortening an
d RS incorporated similar amounts of air, but the air cell numbers dec
reased as increasing levels of shortening were replaced by RS. As the
level of shortening replacement increased, cake crumb became more comp
act. A high degree of shortening replacement also reduced the volume a
nd firmed the cake. However, when RS was used at a low replacement lev
el (12.5%), yellow layer cake quality was improved. RS in the cake bat
ter or cake crumb could be detected in samples in which 50% of the sho
rtening was replaced by RS.