BIS-ADDUCTS FORMED BY NICKEL(II) AND ZINC(II) CHELATES OF PYRIDINE-2-(1H)THIONES WITH NITROGEN DONORS

Authors
KHALIFA MA HASSAAN AMA
Citation
Ma. Khalifa et Ama. Hassaan, BIS-ADDUCTS FORMED BY NICKEL(II) AND ZINC(II) CHELATES OF PYRIDINE-2-(1H)THIONES WITH NITROGEN DONORS, Transition metal chemistry, 19(1), 1994, pp. 28-30
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
1
Year of publication
1994
Pages
28 - 30
Database
ISI
SICI code
0340-4285(1994)19:1<28:BFBNAZ>2.0.ZU;2-9
Abstract
The bis-adducts formed by nickel(II) and zinc(II) chelates of 3-cyano- 4-aryl-6-phenyl pyridine-2-(1H)thiones with pyridine and N-methylimida zole have been prepared and characterized by microelemental analyses, i.r., u.v., vis., and H-1 n.m.r. spectra and magnetic measurements. Ow ing to Lewis acid-base interactions, the diamagnetic square planar nic kel(II) or zinc(II) chelates interact with two molecules of pyridine o r N-methylimidazole in the two axial positions forming the correspondi ng octahedral bis-adducts.