A SOLID-STATE ESR STUDY OF MANGANESE(II) HALIDE-TRIPHENYLPHOSPHINE OXIDE COMPLEXES

Authors
LOBANA TS BALA N
Citation
Ts. Lobana et N. Bala, A SOLID-STATE ESR STUDY OF MANGANESE(II) HALIDE-TRIPHENYLPHOSPHINE OXIDE COMPLEXES, Transition metal chemistry, 19(1), 1994, pp. 115-116
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
1
Year of publication
1994
Pages
115 - 116
Database
ISI
SICI code
0340-4285(1994)19:1<115:ASESOM>2.0.ZU;2-Q
Abstract
Ph3PO adducts with manganese(II) halides, viz. MnX2(OPPh3)2 (X = Cl or Br) were heated for 1 h and their X-band e.s.r. spectra recorded at r oom temperature. The chloride adduct, MnCl2(OPPh3)2 completely transfo rmed into the symmetrised product, [Mn(OPPh3)4] [MnCl4] at 175 and 225 -degrees-C. The bromide adduct, MnBr2(OPPh3)2, which is probably a mix ture of its nonionic and ionic forms at room temperature, showed hyper fine coupling in the g = 2.029 region.