REDUCTION OF MOLECULAR NITROGEN IN A PROTIC MEDIUM WITH PARTICIPATIONOF FE-S AND MO-FE-S CLUSTERS

Authors
DENISOV NT SHUVALOVA NI SHILOV AE PASYNSKII AA KOLOBKOV BI EREMENKO IL
Citation
Nt. Denisov et al., REDUCTION OF MOLECULAR NITROGEN IN A PROTIC MEDIUM WITH PARTICIPATIONOF FE-S AND MO-FE-S CLUSTERS, Kinetics and catalysis, 34(5), 1993, pp. 771-772
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
5
Year of publication
1993
Pages
771 - 772
Database
ISI
SICI code
0023-1584(1993)34:5<771:ROMNIA>2.0.ZU;2-K
Abstract
The nitrogen-fixing activity of seven (Fe-S) and Mo-, V-, Pd - (Fe-S) clusters in methanol is studied, with (P-C6H4)nLi as a reducing agent. In the presence Of Mo2Fe7S8(CO)22, the reduction of molecular nitroge n into ammonia occurs in a catalytic manner.