THE NATURE OF ELECTRON-TRANSFER IN OXIDE CATALYSTS .1. THE FORMATION OF PARAMAGNETIC PALLADIUM IONS IN PD Y2O3 AND PD/LA2O3/

Authors
FILIMONOV IN IKONNIKOV IA LOGINOV AY
Citation
In. Filimonov et al., THE NATURE OF ELECTRON-TRANSFER IN OXIDE CATALYSTS .1. THE FORMATION OF PARAMAGNETIC PALLADIUM IONS IN PD Y2O3 AND PD/LA2O3/, Kinetics and catalysis, 34(5), 1993, pp. 809-816
Citations number
45
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
5
Year of publication
1993
Pages
809 - 816
Database
ISI
SICI code
0023-1584(1993)34:5<809:TNOEIO>2.0.ZU;2-G
Abstract
Palladium-promoted yttrium and lanthanum oxides are capable of stabili zing considerable amounts of paramagnetic Pd+ and Pd3+ ions in the bul k and on the surface. Although all surface palladium ions are coordina tively saturated, they are highly labile in redox processes.