SYNTHESES OF MACRO-AZO-INITIATORS COMPOSED OF POLYISOPRENE OR HYDROGENATED POLYISOPRENE

Citation
H. Terada et al., SYNTHESES OF MACRO-AZO-INITIATORS COMPOSED OF POLYISOPRENE OR HYDROGENATED POLYISOPRENE, Pure and applied chemistry, A31, 1994, pp. 173-178
Citations number
7
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00334545
Volume
A31
Year of publication
1994
Supplement
1-2
Pages
173 - 178
Database
ISI
SICI code
0033-4545(1994)A31:<173:SOMCOP>2.0.ZU;2-K
Abstract
Prepolymers such as polyisoprene diol and hydrogenated polyisoprene di ol were condensed with 4,4'-azobis(4-cyanopentanoyl chloride) to prepa re macro-azo-initiators. Their thermal decomposition behavior, measure d by differential scanning calorimeter, were similar to each other. Th ese macro-azo-initiators were capable for block copolymerization of vi nyl monomers such as styrene and methyl methacrylate.