THE PREPARATION, STABILITY AND REACTIVITY OF PERFLUOROBENZYL-CADMIUM AND PERFLUOROBENZYL-COPPER REAGENTS

Authors
BURTON DJ YANG ZY PLATONOV V
Citation
Dj. Burton et al., THE PREPARATION, STABILITY AND REACTIVITY OF PERFLUOROBENZYL-CADMIUM AND PERFLUOROBENZYL-COPPER REAGENTS, Journal of fluorine chemistry, 66(1), 1994, pp. 23-24
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
66
Issue
1
Year of publication
1994
Pages
23 - 24
Database
ISI
SICI code
0022-1139(1994)66:1<23:TPSARO>2.0.ZU;2-E
Abstract
Perfluorobenzyl bromide reacts readily with acid-washed cadmium powder in DMF at room temperature to give the F-benzylcadmium reagent. Metat hesis of the F-benzylcadmium reagent with Cu(I)Br at -40-degrees-C to -35-degrees-C in DMF affords the F-benzylcopper reagent. The formation of the F-benzylcadmium and -copper reagents was confirmed by F-19 NMR spectral analysis of the reaction mixture and chemical transformation s.