DISUBSTITUTION ON HEXAFLUOROBENZENE WITH N-METHYLFORMAMIDES

Authors
KOPPANG R GRACE D
Citation
R. Koppang et D. Grace, DISUBSTITUTION ON HEXAFLUOROBENZENE WITH N-METHYLFORMAMIDES, Journal of fluorine chemistry, 66(1), 1994, pp. 27-30
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
66
Issue
1
Year of publication
1994
Pages
27 - 30
Database
ISI
SICI code
0022-1139(1994)66:1<27:DOHWN>2.0.ZU;2-H
Abstract
Nucleophilic attack on hexafluorobenzene by N-methylformamide, treated with different bases, gave N-methyl-2,3,4,5,6-pentafluoroformanilide, -dimethyl-2,3,5,6-tetrafluorophenylene-1,4-diamine and dimethyl-2,3,5 ,6-tetrafluorophenylene-1,4-diamine. The substituted benzenes could be hydrolyzed to N-methyl-2,3,4,5,6-pentafluoroaniline and dimethyl-2,3, 5,6-tetrafluorophenylene-1,4-diamine.