ELECTRODE WITH ELECTROCHEMICALLY DEPOSITED ETRAMETHYLTETRA-3,4-PYRIDINOPORPHYRAZINO-COBALT(I) FOR DETECTION OF SULFIDE ION

Authors
TSE YH JANDA P LEVER ABP
Citation
Yh. Tse et al., ELECTRODE WITH ELECTROCHEMICALLY DEPOSITED ETRAMETHYLTETRA-3,4-PYRIDINOPORPHYRAZINO-COBALT(I) FOR DETECTION OF SULFIDE ION, Analytical chemistry, 66(3), 1994, pp. 384-390
Citations number
57
Categorie Soggetti
Chemistry Analytical
Journal title
Analytical chemistry → ACNP
ISSN journal
00032700
Volume
66
Issue
3
Year of publication
1994
Pages
384 - 390
Database
ISI
SICI code
0003-2700(1994)66:3<384:EWEDE>2.0.ZU;2-I
Abstract
Electroreduction of etramethyltetra-3,4-pyridinoporphyrazinocobalt(II) in aqueous buffer phosphate solution leads to the deposition of an in soluble tetrapyridinoporphyrazinocobalt(I) phthalocyanine film on the highly oriented pyrolytic graphite (HOPG) electrode. This modified HOP G electrode has been further coated with Nafion or Tosflex ion-exchang e membranes and used in the determination of concentration of sulfide ion and 2-mercaptoethanol by direct potentiometry.