THE STRUCTURE OF ACTIVE-SITES IN SUPPORTED PALLADIUM CATALYSTS FOR COMPLETE OXIDATION ACCORDING TO EXAFS DATA

Authors
KOCHUBEI DI STAROSTINA TG TSYRULNIKOV PG ZAMARAEV KI
Citation
Di. Kochubei et al., THE STRUCTURE OF ACTIVE-SITES IN SUPPORTED PALLADIUM CATALYSTS FOR COMPLETE OXIDATION ACCORDING TO EXAFS DATA, Kinetics and catalysis, 34(4), 1993, pp. 641-645
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
4
Year of publication
1993
Pages
641 - 645
Database
ISI
SICI code
0023-1584(1993)34:4<641:TSOAIS>2.0.ZU;2-0
Abstract
The structure of active sites in supported Pd catalysts for complete o xidation (0.3 - 0.4 wt % Pd) was studied by the EXAFS method. Both fre sh samples and catalysts having reached steady-state activity in butan e oxidation were investigated. It was shown that the catalytic activit y of Pd/La-Al2O3 correlated with the Pd-Pd distance in the oxide struc ture of an active center.