FORMATION AND DECOMPOSITION OF MOLYBDATE STRUCTURES IN HYDROPROTREATMENT CATALYSTS UNDER IRRADIATION BY A FAST-ELECTRON BEAM OF UP TO 2.0 MEV ENERGY

Authors
LUNIN VV MIROSHNICHENKO II SERGIENKO SA SOLOVETSKII YI CHUKIN GD
Citation
Vv. Lunin et al., FORMATION AND DECOMPOSITION OF MOLYBDATE STRUCTURES IN HYDROPROTREATMENT CATALYSTS UNDER IRRADIATION BY A FAST-ELECTRON BEAM OF UP TO 2.0 MEV ENERGY, Kinetics and catalysis, 34(4), 1993, pp. 658-662
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
4
Year of publication
1993
Pages
658 - 662
Database
ISI
SICI code
0023-1584(1993)34:4<658:FADOMS>2.0.ZU;2-N
Abstract
The structure of the Ni-Mo/Al2O3 catalysts irradiated by an intense fa st-electrons beam of 1.2 MeV energy generated by a linear accelerator is studied. The sequence of the radiation-thermal formation and decomp osition of the surface and bulk Al-2(MoO4)(3) phases, xNiO . MoO3 . yH (2)O solid solution, and alpha- and beta-NiMoO4 modifications in the e lectron-beam radiation field is analyzed.