MARINE-BACTERIA .7. ENZYMATIC BROMINATION OF PSEUDILINS AND RELATED HETEROARYLPHENOLS WITH A CHLOROPEROXIDASE FROM STREPTOMYCES-AUREOFACIENS TU-24

Authors
LAATSCH H PUDLEINER H PELIZAEUS B VANPEE KH
Citation
H. Laatsch et al., MARINE-BACTERIA .7. ENZYMATIC BROMINATION OF PSEUDILINS AND RELATED HETEROARYLPHENOLS WITH A CHLOROPEROXIDASE FROM STREPTOMYCES-AUREOFACIENS TU-24, Liebigs Annalen der Chemie, (1), 1994, pp. 65-71
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Liebigs Annalen der Chemie → ACNP
ISSN journal
01702041
Issue
1
Year of publication
1994
Pages
65 - 71
Database
ISI
SICI code
0170-2041(1994):1<65:M.EBOP>2.0.ZU;2-K
Abstract
During the bromination of various substituted synthetic phenyl pyrrole s with a chloroperoxidase from Streptomyces aureofaciens Tu 24, mixtur es of bromopyrroles are obtained which are not easily accessible by ch emical methods. According to the structure of the pyrroles and the kin etics of their transformation, the reaction centre of the enzyme is si tuated in a slitlike cavity of about 4 X 7 X 8 angstrom.