SYNTHESIS, SPECTRAL AND ELECTROCHEMICAL-BEHAVIOR OF ALPHA-DIIMINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II) WITH 3,4-DIHYDROXYBENZOIC ACID

Authors
ANBALAGAN V SRIVASTAVA TS
Citation
V. Anbalagan et Ts. Srivastava, SYNTHESIS, SPECTRAL AND ELECTROCHEMICAL-BEHAVIOR OF ALPHA-DIIMINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II) WITH 3,4-DIHYDROXYBENZOIC ACID, Polyhedron, 13(2), 1994, pp. 291-299
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
2
Year of publication
1994
Pages
291 - 299
Database
ISI
SICI code
0277-5387(1994)13:2<291:SSAEOA>2.0.ZU;2-A
Abstract
Eight complexes of the formula [M(N-N)(DHBA)] {where M = Pd-II or Pt-I I, N-N = 2,2'-bipyridine (BPY), 2,2'-biquinoline (BIQ), 4,7-diphenyl-1 ,10-phenanthroline (DPP), 1,10-phenanthroline (PHEN) and DHBA is the d ianion of 3,4-dihydroxybenzoic acid} were prepared and characterized b y chemical analysis, IR and H-1 NMR spectroscopy. These complexes were found to show a ligand-to-ligand charge-transfer (LLCT) band. The ene rgies of these bands have been compared with the electrochemical data.