Ap. Hitchcock et al., POLARIZATION DEPENDENCE OF THE SIK-EDGE X-RAY-ABSORPTION SPECTRA OF SI-GE ATOMIC LAYER SUPERLATTICES, Surface science, 301(1-3), 1994, pp. 260-272
The polarization dependence of the SiK-edge X-ray absorption spectra o
f several [(Si)(m)(Ge)(n)](p) atomic layer superlattice (ALS) material
s grown on both Si(100) and Ge(100) have been investigated using plane
polarized synchrotron radiation. These spectra exhibit sharp, polariz
ation dependent, Si 1s --> conduction band (CB) resonance features whi
ch are absent in the spectrum of amorphous Si (a-Si). Subtraction of t
he spectrum of a-Si from that of the crystalline ALS materials is used
to isolate the conduction band structure. A constrained curve fit ana
lysis of up to eight data files simultaneously has been used to quanti
tatively analyze the signal. The CB structure is composed of number of
polarization independent components and several polarization dependen
t components. In [(Si)(2)(Ge)(6)](40)/Ge(100) the lowest energy transi
tion at 1839.1 eV is polarized along the surface normal (the growth di
rection) while a doublet structure centred at 1841 eV is polarized in
the surface plane (perpendicular to the growth direction). A similar s
pectral pattern is found in [(Si)(6)(Ge)(2)](48)/Si(100) but the polar
ization effect is weaker and the sense of the polarization effect is r
eversed. The polarization dependent signal is attributed to anisotropi
c states associated with strain-induced tetragonal distortions in the
strained-ALS materials.