N. Fatouros et al., CONTRIBUTION TO THE STUDY OF DIFFERENTIAL-PULSE POLAROGRAPHY IN THE CASE OF QUASI-REVERSIBLE AND IRREVERSIBLE SIMPLE REACTIONS, Journal of electroanalytical chemistry [1992], 364(1-2), 1994, pp. 135-141
An exhaustive theoretical analysis of differential pulse polarography,
irrespective of the rate of charge transfer, based on the model of pl
ane non-convective diffusion, is presented. The theoretical treatment
is valid in the case of redox systems without chemical complication or
reactant adsorption. This study allows the characterization and quant
itative description of quasi-reversible waves. It also shows how the s
ensitivity of the method can be improved for irreversible reactions.