ANALYTICAL PERFORMANCE OF DIFFERENTIAL-PULSE POLAROGRAPHY IN THE CASEOF NON-REVERSIBLE SIMPLE REACTIONS

Citation
D. Krulic et al., ANALYTICAL PERFORMANCE OF DIFFERENTIAL-PULSE POLAROGRAPHY IN THE CASEOF NON-REVERSIBLE SIMPLE REACTIONS, Journal of electroanalytical chemistry [1992], 364(1-2), 1994, pp. 143-147
Citations number
11
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
364
Issue
1-2
Year of publication
1994
Pages
143 - 147
Database
ISI
SICI code
Abstract
The behaviour of quasi-reversible and irreversible waves for different ial pulse polarography (DPP) performed at dropping and static mercury drop electrodes, was studied as a function of the first polarization t ime, the pulse duration and the potential step amplitude. The experime ntal results confirm the theoretical predictions and show that for slo w reactions a decrease in the first polarization time and an increase in the potential step amplitude yield a real improvement in sensitivit y.