THE AGGREGATION OF COMPLEX-REACTION MECHANISMS .2. KINETIC SYSTEMS

Authors
LEBEDEVA SL SPIVAK SI YABLONSKII GS
Citation
Sl. Lebedeva et al., THE AGGREGATION OF COMPLEX-REACTION MECHANISMS .2. KINETIC SYSTEMS, Kinetics and catalysis, 34(6), 1993, pp. 993-997
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
34
Issue
6
Year of publication
1993
Pages
993 - 997
Database
ISI
SICI code
0023-1584(1993)34:6<993:TAOCM.>2.0.ZU;2-Z
Abstract
The procedure of lumping analysis is developed for complex chemical re actions. The number of ''lumping reactions'' of the contacted descript ion equals the number of the independent routes in the sense of the Ho riuti-Temkin theory of stationary reactions. An algorithm for obtainin g the contracted description is illustrated by examples of the isomeri zation reaction, hydrogenolysis of n-pentane on platinum and nickel, a nd hydrogenation of iron carbide.