The acid volcanic glass deposits in Armenia were characterized using p
etrochemical and glass-chemical methods. This paper aims to help inter
pret the extrusion mechanism of such lava flows, 50 to 250 m thick, wi
th respect to the chemical composition of the matrix glass, crystallin
e inclusions and volatile content. The microstructure of the Armenian
obsidian indicates that the lava flow and the formation of magnetite w
hiskers are two independent processes. Crystallization of Fe-Mn-pyroxe
ne and euhedral magnetite probably occurred in the melt during the ext
rusion period. During a second heating process, the pyroxene decompose
d simultaneously with an oxidation process and magnetite formed. The f
orm of the whiskers indicates that viscosity during the melt must have
been lower than 10(-4) Pas. This therefore would mean that the solidi
fied melt was reheated up to at least 1000 degrees C.