Three sandy Luvisols from Alberta were studied through mineral investi
gations and geochemical prediction based on the ionic composition of t
he in situ soil solution to evaluate the stability and formation of mi
nerals. The transformation of phyllosilicates in this study appears to
be dominated by the vermiculitization of mica and to a lesser extent
of chlorite. Hydroxy interlayered phyllosilicate is also observed thro
ughout the sola. There are good agreements between geochemical predict
ions and mineral determination for calcite, dolomite, goethite, hemati
te and lepidocrocite. These observation suggest that a geochemical mod
el using data from the composition of in situ soil solution can be use
d to evaluate the stability and formation of the low quantities of the
common carbonates, oxides and oxyhydroxides. The unique micro- or pal
eo-environments are believed to be responsible for the disagreement be
tween the model and the mineral observation for gypsum while the ''ant
i-gibbsite'' effect of organic components may be responsible for the n
on-formation of gibbsite.