The organic matter from the A horizons of five soils developed under a
shrubby cover and under pine groves in a Mediterranean high-mountain
area has been studied. The characteristics of humic acids (HA) are com
pared with those reported by other researchers in a variety of environ
mental conditions. The organic matter from pine groves has a higher C/
N ratio, a greater content in fresh or little-transformed organic matt
er, and a lower humic extract than that of shrublands. In general, the
humic acids show a low humification index, with greater relative prop
ortion of aliphatic chains and less condensed aromatic-type structure
as the pH and base saturation diminish. The climatic extremes which ty
pify these ecosystems, very cold winters and very dry summers, togethe
r with the acidity and low base saturation of the soils, seem to be th
e determining causes of the low-humification index. Felbeck's hypothes
is of alteration of plant components appears to be the principal proce
ss controlling the humic-acid evolution of the organic matter in these
soils.