BIACETYLDIHYDRAZONE AND BRIDGE CYANIDE COMPLEXES

Authors
BARQUIN M GARMENDIA MJG
Citation
M. Barquin et Mjg. Garmendia, BIACETYLDIHYDRAZONE AND BRIDGE CYANIDE COMPLEXES, Journal of coordination chemistry, 39(3-4), 1996, pp. 211-218
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
39
Issue
3-4
Year of publication
1996
Pages
211 - 218
Database
ISI
SICI code
0095-8972(1996)39:3-4<211:BABCC>2.0.ZU;2-B
Abstract
Dinuclear complexes of biacetyldihydrazone (BdH) and bridging cyanide groups, (BdH)(2) M(NC)(2)Ni(CN)(2).H2O, M=Co(II), Ni(II) or Zn(II); (B dH)M(NC)(2)Ni(CN)(2).H2O, M=Cu(II) or Zn(II); (BdH)Cu(NC)(2)Zn(CN)(2). H2O and (BdH)(2)Ni(CN)(2)Zn(CN)(2).H2O were prepared by reaction of [M (BdH)(3)](NO3)(2) and K-2[Ni(CN)(4)] or K-2[Zn(CN)(2)]. The complexes are insoluble and have been characterized by infrared and electronic s pectroscopies. Magnetic subsceptibilities in the 4.2-290K range show C urie - Weiss behaviour for the paramagnetic samples.