ACID-BASE CHEMISTRY OF HIGH-ELEVATION STREAMS IN THE GREAT SMOKY MOUNTAINS

Longitudinal and temporal variations in water chemistry were measured in several low-order, high-elevation streams in the Great Smoky Mounta ins to evaluate the processes responsible for the acid-base chemistry. The streams ranged in average base flow ANC from -30 to 28 mu eq L(-1 ) and in pH from 4.54 to 6.40. Low-ANC streams had lower base cation c oncentrations and higher acid anion concentrations than did the high-A NC streams. NO3- and SO42- were the dominant acid anions. NO3- was der ived from a combination of high leaching of nitrogen from old-growth f orests and from high rates of atmospheric deposition. Streamwater SO42 - was attributed to atmospheric deposition and an internal bedrock sou rce of sulfur (pyrite). Although dissolved Al concentrations increased with decreasing pH in the study streams, the concentrations of inorga nic monomeric Al did not follow the pattern expected from equilibrium with aluminum trihydroxide or aluminum silicate phases. During storm e vents, pH and ANC declined by as much as 0.5 units and 15 mu eq L(-1), respectively, at the downstream sites. The causes of the episodic aci dification were increases in SO42- and DOC.