THE POLYMERIC COPPER(II) COMPLEX, 2,2'-BIPYRIDINE-N,N'-(MU-NICOTINATO-O,O'N) MONOAQUACOPPER(II) NITRATE DIHYDRATE

Authors
XU DJ XIE AL XU YZ ZHANG CG CHEN WG
Citation
Dj. Xu et al., THE POLYMERIC COPPER(II) COMPLEX, 2,2'-BIPYRIDINE-N,N'-(MU-NICOTINATO-O,O'N) MONOAQUACOPPER(II) NITRATE DIHYDRATE, Journal of coordination chemistry, 39(3-4), 1996, pp. 273-280
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
39
Issue
3-4
Year of publication
1996
Pages
273 - 280
Database
ISI
SICI code
0095-8972(1996)39:3-4<273:TPCC2>2.0.ZU;2-V
Abstract
The nicotinate complex of Cu(II), 2,2'-bipyridine(nicotinato)monoaquac opper(II) nitrate dihydrate has been prepared and its crystal structur e has been determined by means of X-ray methods. The nicotinate anions bridge adjacent Cu(II) atoms through both the pyridine N atom and the carboxyl group to form infinite chains. The carboxyl group of the nic otinate anion coordinates to the Cu(II) atom as a chelate. Based on th e molecular structure the infrared spectrum is discussed.