COMPLEX-FORMATION BETWEEN ALKALI AND ALKALINE-EARTH CATIONS AND CROWN-ETHERS AND CRYPTANDS IN AQUEOUS-SOLUTION

Authors
BUSCHMANN HJ CLEVE E SCHOLLMEYER E
Citation
Hj. Buschmann et al., COMPLEX-FORMATION BETWEEN ALKALI AND ALKALINE-EARTH CATIONS AND CROWN-ETHERS AND CRYPTANDS IN AQUEOUS-SOLUTION, Journal of coordination chemistry, 39(3-4), 1996, pp. 293-298
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
39
Issue
3-4
Year of publication
1996
Pages
293 - 298
Database
ISI
SICI code
0095-8972(1996)39:3-4<293:CBAAAC>2.0.ZU;2-4
Abstract
The complexation of alkali and alkaline earth cations in aqueous solut ion by crown ethers, diaza crown ethers and cryptands has been studied using pH-metric, calorimetric and competitive calorimetric titrations . Use of different experimental techniques makes it possible for the f irst time to obtain a large number of stability constants and thermody namic parameters for complexation between these cations and ligands.