We describe a new form of calorimeter designed for use in gaseous and
vacuum environments which can sense chemical reactions with an estimat
ed sensitivity limit of approximate to 1 pJ. The device is based on a
micromechanical Si lever coated with a thick layer of Al upon which a
sample in the form of a thin layer is fixed or deposited. Heat fluxes
are detected by measuring the cantilever deflection induced by the dif
ferential thermal expansion of the lever (bimetallic effect) using the
optical position sensor from a force microscope. The limit of sensiti
vity to local temperature changes is approximate to 10(-5) K at 300 K.
Using this technique the catalytic conversion of H-2 + O-2 to form H2
O over a thin Pt overcoated layer is observed to exhibit self-sustaine
d oscillations in the reaction rate on the macroscopic scale.