THE COMPARISON OF THE INFLUENCE OF IONIC POTENTIAL AND ELECTRONEGATIVITY OF SELECTED METALS AND HALOGENS ON THE ELECTRONIC SYSTEM OF BENZOIC-ACID

Authors
KOCZON P LEWANDOWSKI W MOSCIBRODA P PRIEBE W WIECKOWSKA E
Citation
P. Koczon et al., THE COMPARISON OF THE INFLUENCE OF IONIC POTENTIAL AND ELECTRONEGATIVITY OF SELECTED METALS AND HALOGENS ON THE ELECTRONIC SYSTEM OF BENZOIC-ACID, Canadian journal of applied spectroscopy, 41(6), 1996, pp. 144-149
Citations number
21
Categorie Soggetti
Spectroscopy
Journal title
Canadian journal of applied spectroscopy → ACNP
ISSN journal
11837306
Volume
41
Issue
6
Year of publication
1996
Pages
144 - 149
Database
ISI
SICI code
1183-7306(1996)41:6<144:TCOTIO>2.0.ZU;2-R
Abstract
Lithium, sodium, potassium, rubidium and cesium salts of para halogeno benzoic acids were investigated to study the influence of halogens and metals on the electronic system of aromatic ring. This was done by H- 1 and C-13 NMR, IR and Raman spectroscopy and semiempirical calculatio ns (AMI method). It was shown that ionic potentials and electronegativ ities of halogens and metals are the main factors responsible for pert urbation of electronic charge distribution in the ring.