REMARKABLE STEREOCHEMICAL INVERSION IN SOME HECK ARYLATION REACTIONS - A MECHANISTIC PROPOSAL

Citation
Kf. Mcclure et al., REMARKABLE STEREOCHEMICAL INVERSION IN SOME HECK ARYLATION REACTIONS - A MECHANISTIC PROPOSAL, Journal of organic chemistry, 59(2), 1994, pp. 355-360
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00223263
Volume
59
Issue
2
Year of publication
1994
Pages
355 - 360
Database
ISI
SICI code
0022-3263(1994)59:2<355:RSIISH>2.0.ZU;2-Z
Abstract
Internal arylation reactions of enol ethers were used to form the 1,5- epoxybenzazocine ring system of FR 900482. An interesting inversion pr ocess was observed for Z-enol ethers.