Optical pumping strongly enhances nuclear spin polarizations in an n-d
oped GaAs/AlGaAs multiple quantum well, allowing NMR signals of the Ga
As wells to be investigated by direct, radio-frequency detection in a
7.05 T field. The optically pumped NMR signals exhibit unanticipated d
ependences on the pumping wavelength, polarization, and power. The tem
perature dependence of the Ga-71 NMR Knight shift is consistent with a
g value of -0.49 +/- 0.02 for electrons in the wells, with no exchan
ge enhancement. We present evidence that the doped and photoexcited el
ectrons do not reach a common spin temperature under optical pumping.