O. Yamazaki et al., IN-SITU RAPID THERMAL NITRIDATION OF COLLIMATED TITANIUM BY PHYSICAL VAPOR-DEPOSITION AS A BLANKET TUNGSTEN BARRIER, JPN J A P 1, 33(1B), 1994, pp. 466-469
A very thin bilayered titanium nitride/titanium barrier was obtained f
rom in situ rapid thermal nitridation (RTN) for collimated Ti by physi
cal vapor deposition for blanket tungsten plug. Ti with in situ RTN re
sults in fine barrier properties compared with those by RTN with expos
ure to air after Ti deposition. Furthermore, this thinner film without
the re-entrant profile at the contact shoulder was effective for comp
lete contact filling at 0.25 mu m diameter with the aspect ratio of 4.
This is one of the barrier technologies applicable to quarter-micron
devices.