Formation of high-precision fine resist patterns has been achieved by
an effective removal of dissolved resist polymers, that is, the reacti
on products of the development process. Also, it has been found that t
he reaction products give rise to the degradation of the resist contra
st, resist sensitivity, and process margins. In order to remove the re
action products, two techniques have been employed, namely physical me
thod of development with agitation (ultrasonic waves or with a stirrer
) and chemical method of adding surfactant to the developer. By combin
ing physical and chemical methods, the dissolved polymers have been ef
fectively removed, thus allowing the resist to reveal its inherent pat
terning pertormance.