Perturbation theory is applied to rectangular-core coupled waveguides,
whose cladding can be homogeneous or not. Second-order corrections ar
e evaluated for the phase constants of the guided modes and for the co
upling coefficient. This requires the full spectrum of radiation modes
, which are found within the same approximation as Marcatili's guided
modes. It is found that the second-order terms are negligible in most
cases of practical interest. However, there are cases for which these
terms are so large that the usual first-order theory collapses.