SYNTHESIS VIA A CYCLIC DIOXATRICHLOROPHOSPHORANE OF 1,3-DIBENZYL-2-PHOSPHONOOXY CITRATE

Authors
PANKOWSKI AH MEEHAN JD SALLIS JD
Citation
Ah. Pankowski et al., SYNTHESIS VIA A CYCLIC DIOXATRICHLOROPHOSPHORANE OF 1,3-DIBENZYL-2-PHOSPHONOOXY CITRATE, Tetrahedron letters, 35(6), 1994, pp. 927-930
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
6
Year of publication
1994
Pages
927 - 930
Database
ISI
SICI code
0040-4039(1994)35:6<927:SVACDO>2.0.ZU;2-L
Abstract
Phosphorylation of tribenzyl citrate with PCl5 proceeds via a cyclic d ioxatrichlorophosphorane and results in the formation of 1,3-dibenzyl- 2-phosphonooxy citrate. A mechanism for the phosphorylation and ester hydrolysis is proposed and the usefulness of the diester for producing triesters is discussed.