ENZYMATIC TRANSFORMATION OF GLYCEROGLYCOLIPIDS INTO SN-1 AND SN-2 LYSOGLYCEROGLYCOLIPIDS BY USE OF RHIZOPUS-ARRHIZUS LIPASE

Authors
MURAKAMI N MORIMOTO T IMAMURA H NAGATSU A SAKAKIBARA J
Citation
N. Murakami et al., ENZYMATIC TRANSFORMATION OF GLYCEROGLYCOLIPIDS INTO SN-1 AND SN-2 LYSOGLYCEROGLYCOLIPIDS BY USE OF RHIZOPUS-ARRHIZUS LIPASE, Tetrahedron, 50(7), 1994, pp. 1993-2002
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
7
Year of publication
1994
Pages
1993 - 2002
Database
ISI
SICI code
0040-4020(1994)50:7<1993:ETOGIS>2.0.ZU;2-T
Abstract
Lipase from Rhizopus arrhizus catalyzed deacylation of two classes of glyceroglycolipids, monogalactosyl diacylglycerol(MGDG), and digalacto syl diacylglycerol(DGDG), proceeded regiospecifically to furnish sn-1 lysoglyceroglycolipids quantitatively. The lipase also catalyzed compl ete acyl migration of sn-1 lysoglycerogalacto-lipids leading to sn-2 l ysoglycerogalactolipids.