THERMAL-PROPERTIES OF A NEW ORGANOMETALLIC NONLINEAR-OPTICAL MATERIAL, TRIALLYLTHIOUREA MERCURY BROMIDE (ATMB)

Authors
HOU WB YANG ZH LIU MG YUAN DR XU D ZHANG N YU WT BING YH SUN SY TAO XT JIANG MH
Citation
Wb. Hou et al., THERMAL-PROPERTIES OF A NEW ORGANOMETALLIC NONLINEAR-OPTICAL MATERIAL, TRIALLYLTHIOUREA MERCURY BROMIDE (ATMB), Materials letters, 18(4), 1994, pp. 207-210
Citations number
8
Categorie Soggetti
Material Science","Physics, Applied
Journal title
Materials letters → ACNP
ISSN journal
0167577X
Volume
18
Issue
4
Year of publication
1994
Pages
207 - 210
Database
ISI
SICI code
0167-577X(1994)18:4<207:TOANON>2.0.ZU;2-K
Abstract
Crystallographic, thermal expansion and specific heat data obtained fo r a single crystal of a new organometallic nonlinear optical material, triallylthiourea mercury bromide (ATMB), are reported. It is trigonal (space and point groups are R3c and C3v respectively) with lattice pa rameters a=b=11.580 Angstrom, c=28.939 Angstrom, V=3375 Angstrom(3). T here are six formula units per cell and the density is 2.10 g/cm(3). T he second harmonic generation intensity, obtained on a powder sample, is 2.5 times greater than that of urea.