INTERACTION OF RFLUOROBUTYL-3,3-DI(PERFLUOROMETHYL)-2-AZIRIDINONE WITH WEAK NUCLEOPHILES

Authors
DELTSOVA DI GAMBARYAN NP
Citation
Di. Deltsova et Np. Gambaryan, INTERACTION OF RFLUOROBUTYL-3,3-DI(PERFLUOROMETHYL)-2-AZIRIDINONE WITH WEAK NUCLEOPHILES, Russian chemical bulletin, 42(2), 1993, pp. 333-336
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
2
Year of publication
1993
Pages
333 - 336
Database
ISI
SICI code
1066-5285(1993)42:2<333:IORW>2.0.ZU;2-0
Abstract
The title perfluoro-alpha-lactam (1) was found to react with N,N-dimet hylformamide to give initially a betaine (2) which undergoes ring enla rgement to produce the isomeric dimethylamino-3,4,4-tri(perfluoroalkyl )substituted 5-oxazolidone (3). Related betaines were also obtained on reaction of 1 with pyridine, quinoline, benzalaniline, and p-dimethyl aminobenzaldehyde.