DUAL CHIRAL RECOGNITION SYSTEM INVOLVING CYCLODEXTRIN DERIVATIVES IN CAPILLARY ELECTROPHORESIS

Authors
MAYER S SCHLEIMER M SCHURIG V
Citation
S. Mayer et al., DUAL CHIRAL RECOGNITION SYSTEM INVOLVING CYCLODEXTRIN DERIVATIVES IN CAPILLARY ELECTROPHORESIS, The Journal of microcolumn separations, 6(1), 1994, pp. 43-48
Citations number
15
Categorie Soggetti
Chemistry Analytical
Journal title
The Journal of microcolumn separations → ACNP
ISSN journal
10407685
Volume
6
Issue
1
Year of publication
1994
Pages
43 - 48
Database
ISI
SICI code
1040-7685(1994)6:1<43:DCRSIC>2.0.ZU;2-Y
Abstract
An immobilized chiral stationary phase, Chirasil-Dex, coated onto the inner 'surface of a 50 mu m i.d. capillary and cyclodextrin derivative s added to the running buffer were simultaneously used for the study o f enantiomer separations by capillary electrophoresis. Dependent on th e cyclodextrin concentration in the mobile phase, a reversal of the el ution order of enantiomers due to dual chiral recognition mechanisms w as observed.