INTRAMOLECULAR BASE STABILIZATION OF COBALT-GALLIUM AND COBALT-INDIUMCOMPOUNDS

Authors
OLAZABAL CA GABBAI FP COWLEY AH CARRANO CJ MOKRY LM BOND MR
Citation
Ca. Olazabal et al., INTRAMOLECULAR BASE STABILIZATION OF COBALT-GALLIUM AND COBALT-INDIUMCOMPOUNDS, Organometallics, 13(2), 1994, pp. 421-423
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
2
Year of publication
1994
Pages
421 - 423
Database
ISI
SICI code
0276-7333(1994)13:2<421:IBSOCA>2.0.ZU;2-X
Abstract
The intermetallic derivatives [{(2,6-Me2-NCH2)2C6H3}M{Co(CO)4}2] (M = Ga (1); M = In (2)) have been prepared. X-ray analysis reveals that on ly one of the dimethylamine groups is coordinated to Ga in 1 and as a consequence the CGaCo2 moiety is pyramidal; the indium analogue 2 poss esses a distorted-trigonal-bipyramidal geometry and a planar CInCo2 un it.