SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES)

Authors
ANDO W OHTAKI T KABE Y
Citation
W. Ando et al., SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES), Organometallics, 13(2), 1994, pp. 434-435
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
2
Year of publication
1994
Pages
434 - 435
Database
ISI
SICI code
0276-7333(1994)13:2<434:SSAPOB>2.0.ZU;2-3
Abstract
The reaction of bis[bis(trimethylsilyl)methyl]-germylene (1) with N-(a zidosilyl)germanimines 3a,b at room temperature gave bis(germanimines) 4a,b in quantitative yield whose structures have been confirmed by si ngle-crystal X-ray diffraction. The photolysis of 4a gave the cyclic s ilanimine 6 as an unexpected product.