PREPARATION OF MONO(GERMYL)NITRILIMINES AND BIS(GERMYL)NITRILIMINES FROM GERMYLENES AND STANNYL DIAZO DERIVATIVES

Authors
LEUE C REAU R NEUMANN B STAMMLER HG JUTZI P BERTRAND G
Citation
C. Leue et al., PREPARATION OF MONO(GERMYL)NITRILIMINES AND BIS(GERMYL)NITRILIMINES FROM GERMYLENES AND STANNYL DIAZO DERIVATIVES, Organometallics, 13(2), 1994, pp. 436-438
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
2
Year of publication
1994
Pages
436 - 438
Database
ISI
SICI code
0276-7333(1994)13:2<436:POMABF>2.0.ZU;2-D
Abstract
(Silyl)(germyl)- and bis(germyl)nitrilimines 2 and 5 are obtained by a dding [bis(trimethylsilyl)-methyl] (pentamethylcyclopentadienyl)germyl ene (1) to (triisopropylsilyl)(trimethylstannyl)diazomethane and bis(t rimethylstannyl)diazomethane, respectively; the reaction mechanism is discussed.