STEREOCHEMICAL NONRIGIDITY IN A CHELATED PLATINUM(0)-DIOLEFIN COMPLEX

Authors
BASSINDALE AR BROWN SSD LO P
Citation
Ar. Bassindale et al., STEREOCHEMICAL NONRIGIDITY IN A CHELATED PLATINUM(0)-DIOLEFIN COMPLEX, Organometallics, 13(2), 1994, pp. 738-740
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
2
Year of publication
1994
Pages
738 - 740
Database
ISI
SICI code
0276-7333(1994)13:2<738:SNIACP>2.0.ZU;2-I
Abstract
Stereochemical nonrigidity has been observed in the Pt(0) complex [Pt{ (eta-ViMe2Si)201(P(t)Bu3)] (1a) by NMR spectroscopy. The activation pa rameters have been measured by DNMR3 analysis of the spectra over a ra nge of temperatures. It is concluded that the vinylsiloxane ligand is undergoing a facile dissociation-reassociation process, although a rel ated nondissociative mode involving a rotation about the alkene C-C ax is cannot be completely dismissed.