SYNTHESIS AND CHARACTERIZATION OF A DIMOLYBDENUM (V)COMPLEX

Authors
QIU W LIU JZ ZHENG XF FAN YG SUN CT HUANG QJ ZHANG JW
Citation
W. Qiu et al., SYNTHESIS AND CHARACTERIZATION OF A DIMOLYBDENUM (V)COMPLEX, European journal of solid state and inorganic chemistry, 30(11), 1993, pp. 1039-1048
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
30
Issue
11
Year of publication
1993
Pages
1039 - 1048
Database
ISI
SICI code
0992-4361(1993)30:11<1039:SACOAD>2.0.ZU;2-C
Abstract
A new dimolybdenum (V) complex containing a trityl C6H4Cl)2C(Ph)]2[Mo2 (mu-Cl)3Cl4O2][Mo2(mu-Cl)2Cl4O2 (mu-OCOPh)] has been obtained in the r eaction of PhCl with benzoyl peroxide (PhCO2)2 and MoCl5. Its crystal structure has been determined by X-ray diffraction methods. Spectrosco pic characterization of the compound and ASED-MO calculation of the tr ityl cation are reported.