DISODIUM-LITHIUM CYCLOTRIPHOSPHATE TETRAHYDRATE - NA2LIP3O9.4H2O

Authors
AVERBUCHPOUCHOT MT DURIF A
Citation
Mt. Averbuchpouchot et A. Durif, DISODIUM-LITHIUM CYCLOTRIPHOSPHATE TETRAHYDRATE - NA2LIP3O9.4H2O, European journal of solid state and inorganic chemistry, 30(11), 1993, pp. 1075-1082
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
30
Issue
11
Year of publication
1993
Pages
1075 - 1082
Database
ISI
SICI code
0992-4361(1993)30:11<1075:DCT-N>2.0.ZU;2-L
Abstract
Na2LiP3O9.4H2O corresponds to a new structural arrangement in the fami ly of cyclotriphosphates. This salt is triclinic, with Z = 2 and the f ollowing unit-cell dimensions : a = 6.905(2) b = 9.346(3) c = 9.876(2) angstrom alpha = 95.00(2) beta = 104.36(2) gamma = 107.75(3)degrees T he atomic arrangement, determined with a set of 3778 independent refle ctions down to a final R value of 0.019, is mainly characterized by la rge centrosymmetrical rings built by two P3O9 groups connected by two LiO4 tetrahedra. The three-dimensional hydrogen-bond scheme is given.