P. Ewart, TEMPERATURE-MEASUREMENT BY UV-DEGENERATE 4-WAVE-MIXING, Berichte der Bunsengesellschaft fur Physikalische Chemie, 97(12), 1993, pp. 1625-1630
Citations number
22
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
The derivation of temperatures of gas phase media from spectra generat
ed by DFWM, induced by frequency scanned narrow linewidth lasers, is b
riefly reviewed. The technique of multiplex or broadband DFWM is descr
ibed, by which spectra, and hence temperatures, may be obtained by a s
ingle shot of a novel broadband ''modeless'' laser. Experimental measu
rements of broadband DFWM lineshapes from OH are briefly described and
compared with theoretical predictions. Results of temperature measure
ments in premixed methane/air flames using broadband DFWM spectra are
reported. Systematic errors arising from the effect of absorption are
discussed, improvements to and applications of the technique to turbul
ent media are briefly considered.