J. Xu et J. Warnatz, 2-DIMENSIONAL IMAGING OF OH RADICALS IN SPARK-IGNITION KERNELS BY LASER-INDUCED FLUORESCENCE, Berichte der Bunsengesellschaft fur Physikalische Chemie, 97(12), 1993, pp. 1741-1744
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
Two-dimensional laser-induced fluorescence imaging of OH radicals has
been used to observe the temporal and spatial development of the OH di
stribution during the ignition of a lean methane-air mixture (phi = 0.
56) ignited by an electrical spark. A frequency-doubled dye laser, whi
ch is pumped by a XeCl excimer laser, has been used to excite fluoresc
ence from OH radicals. A series of OH concentration maps from a cross-
section through the ignition kernel during the ignition process have b
een obtained. It can be seen that the gas flow induced by the initial
shock wave from the breakdown phases has a significant influence on th
e development of the ignition kernel. The ignition kernel is produced
by a narrow cyclindrical plasma channel with high temperature, then ex
pands to an ellipsoid during the ignition. At about 1 ms after the ons
et of the spark the ignition kernel expands from the ellipsoid to a to
roidal shape. A flame front emerges from the ignition kernel at about
10 ms.